Pão de Queijo (Brazilian Cheese Bread, and the Gluten-Free Starch Science That Makes It So Chewy)

Prep: 20m
Cook: 22m
baked good
Pão de Queijo (Brazilian Cheese Bread, and the Gluten-Free Starch Science That Makes It So Chewy) - Image

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Ingredients
Servings:6
1cupmilk
1/3cupvegetable oil
1tspsalt
2cuptapioca flour
2eggs
1cupparmesan cheese
1cupmozzarella cheese
Nutrition Facts

Per serving

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Instructions
  1. 1

    Scald the liquids

    Combine the milk, oil, and salt in a saucepan and heat over medium until it just comes to a boil. Here's the whole trick in one step: you want that liquid genuinely hot. When boiling liquid hits tapioca starch, the starch granules swell and partially gelatinize — basically the same move as a tangzhong in milk bread. That pre-cooked, gelatinized starch is what gives the inside its signature gooey, stretchy chew instead of a chalky, powdery crumb.

  1. 2

    Hydrate the tapioca

    Put the tapioca flour in a large bowl and pour the hot liquid over it all at once. Stir hard with a wooden spoon. It will look alarming — lumpy, gluey, clumping into weird strings. That is exactly right. Those strands are the gelatinizing starch doing its job. Let the mixture sit and cool for about 10 minutes, until it's warm rather than hot, so the eggs don't scramble when they go in.

  2. 3

    Beat in eggs and cheese

    Add the eggs one at a time, beating well after each, then mix in the parmesan and mozzarella. The dough will be sticky, soft, and a little stretchy. Worth knowing why it holds together at all: tapioca has zero gluten-forming protein, so unlike a wheat dough there's no gluten network here. All the structure comes from the gelatinized starch plus the egg proteins, which will set firm in the oven and give the balls their walls.

  3. 4

    Shape the balls

    Line a baking sheet with parchment. Lightly oil your hands (the dough is sticky) and roll the dough into balls about 1 1/2 inches across, spacing them 2 inches apart. If the dough is too soft to roll, chill it for 15 minutes first — cooler dough is much easier to shape.

  4. 5

    Bake with steam

    Bake at 400°F for 20 to 25 minutes, until puffed, golden, and hollow-sounding. The puff is pure steam: the moisture trapped in that starchy, eggy dough flashes to steam and inflates each ball from the inside, exactly like a popover, while the egg and starch set the shell. Resist opening the oven in the first 15 minutes — a blast of cool air drops the steam pressure and they'll deflate. Best eaten warm, when the inside is at its stretchiest.

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